BoilingPoint:102-3°/0.5
MolecularWeight:363.22
AlternativeName:TRIMETHYLSILYLTRI-n-BUTYLTIN
SpecificGravity:1.040
HMISKey:2-1-1-X
Formula:C15H36SiSn
RefractiveIndex:1.4880
Application:Reviewofsyntheticutility.1
UndergoescisadditiontoterminalacetyleneswithBu3Sninternal.2
Intermediatefor3-substitutedcyclobutenone.3
Sn-SibondshowntoreactwithCODPt(cod)2andphosphinestoformbis((phosphino)silyl)tinplatinum(ll)complexes,whichinsertintoacetylenes.4
Usedinthesynthesisof?-amidotributylstannanes.5
Reference:1.HandbookofReagentsforOrganicSynthesis,ReagentsforSilicon-MediatedOrganicSynthesis,Fuchs,P.L.Ed.,JohnWileyandSons,Ltd.,2011,p.719-723.
2.Chenard,B.etal.J.Org.Chem.1986,51,3561.
3.Liebeskind,L.S.etal.J.Org.Chem.1994,59,7917.
4.Sagawa,T.etal.Organometallics2003,22,4433.
5. Mita,T.;etal.Synthesis2012,194.
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