Boiling Point: 75°
EINECS Number: 214-673-5
Melting Point: -71°
Molecular Weight: 179.97
Specific Gravity: 1.930
Flashpoint: 12°C (54°F)
HMIS Key: 3-4-2-X
Formula: HCl3Ge
TSCA: TSCA
Application: Pure GeCl2 may be provided by cooling to -30° and pulling vacuum.1,2
Complex with 2 moles ether reduces nitro compounds and ferric chloride.3,4
Hydrogermylates olefins without catalyst.5,6
Undergoes superacid reactions with aromatics.7,8
Reference: 1. Schwarz, R. et al. Z. Anor. Allg. Chem. 1954, 275, 1.
2. Brauer, G. Handbook of Preparative Inorganic Chemistry, 717, Academic, 1963.
3. Craddock, S. et al. Inorg. Chem. 1967, 6, 1751.
4. Creemers, H. et al. J. Organomet. Chem. 1967, 7, 237.
5. Lesbre, M. et al. The Organic Compounds of Germanium, 223, Wiley, 1971.
6. Wolfsberger, W. J. Praktische Chem. 1992, 334, 453.
7. Kolosnikov, S. Main Group Metal Chem. 1989, 12, 305.
8. Kolosnikov, S. Chem. Abstr. 110, 114984u; Izv. Akad. Nauk. Ser. Khim. 1988, 3, 666.
Additional Properties: Hazy liquid
Decomposes >140°, yielding Ge, HCl, GeCl4Vapor pressure, -10°: 9.2 mm
Vapor pressure, 20°: 80 mm
Gelest有机硅产品系列中介绍了常规有机硅油以及热,氟硅酮,亲水和低温等级的设计和工程特性。Gelest有机硅产品线还介绍了可配制为机械,光学,电子和陶瓷应用的涂料,薄膜,固化橡胶和胶粘剂的反应性有机硅。